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GC/TOF MS application: Analyses from complex matrices using BenchTOF-dx

GCxGC/TOF MS: Diesel sample


2D GCxGC/TOF MS plot of diesel 3D GCxGC/TOF MS plot of diesel

Analytical conditions:

BenchTOF-dx TOF MS, Agilent 7890 GC & Zoex GCxGC modulator

  • Column set: BPX5 & BPX50 
  • BenchTOF-dx data converted to .cdf & displayed in GC image display software

Observations:

  • GCxGC customarily utilises flame ionisation detection (FID).
  • Quadrupole MS instruments are unable to scan the wide mass range required for the sharp peaks generated by GCxGC
  • BenchTOF-dx TOF MS is able to measure fast enough (in the range 10 - 800 amu) allowing coupling with GCxGC; peaks typically <80 ms wide can be identified
  • Using the easily installable GCxGC modulator, volatile compounds (C3) through to semi-volatile organic compounds (SVOC) may be trapped & analysed

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